Our research group developed the first gas-solid hydride ion battery that enables efficient hydrogen storage under ambient temperature and pressure, eliminating the need for extreme condition such as high pressure (700 atm) or cryogenic temperatures (-253°C). This battery utilises hydrogen gas as the positive electrode and magnesium metal as the negative electrode. During discharge, hydrogen is converted into hydride ions (H-), while magnesium is converted into magnesium hydride (MgH2); the reverse reactions occur during charging, alloing simultaneous hydrogen and electricity storage.
Key results include:
1) An initial discharge capacity of 1526 mAh g-1, release of ~6.0 wt% hydrogen at 0.3 V and room temperature,
2) >70% capacity retention after 60 cycles, stable operation from −20 to 90°C, and
3) Stacking of the cells powering an LED light.
The system achieves an overall energy efficiency of 93.9%; about one-third higher than conventional thermal hydrogen storage (e.g., Mg/MgH2 systems requiring ~300°C for dehydrogenation). This breakthrough offers a safe, efficient method for hydrogen storage applications.
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